Hi @Sai Pasupuleti you need a feature called supplemental documents. Composite templates allow you to combine multiple templates and documents into a single envelope, including supplemental documents. These supplemental documents can be added as separate CompositeTemplate items within the envelope definition.
I’d suggest opening a support case because this is considering advanced task and there are many conditions when implementing it
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@Sai Pasupuleti keep in mind that all documents in an envelope are rendered internally as PDF files. That means that a DOCX file will be converted to PDF.