@Christo
You can locate the user in the account and delete the Old Federated ID. When they try to login via SSO again, a new ID will be created. You need to have access to Org Admin to do this step.
Org Admin → Users → Locate User → Security → Under Federated ID Actions → Clear
I’m not sure there is a setting to this in Bulk. You can try to Bulk Close users and then open them again. Try it in Demo first.
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